Howdy Back:
TJH- the combustion chamber shape is not too bad. The miss-match of the chamber wedge and the piston dish is unfortunate, but still not too bad. The small diameter bore also helps to minimize knock. The problems are more likely due to the short stroke design, high cylinder pressures and designed to run at low rpms (lugging). Yes, smoothing and rounding any sharp edges in the chambers will help by eliminating hot spots and minimizing carbon build up, both of which can cause pre-ignition. EFI doesn't sound like an option(?) but a computerized knock sensor and timing control would help to deal with higher CR. However, the gain of another point of CR would hardly be worth the effort and expense. Getting to a zero deck height will also help with quench which will minimize spontanious combustion- another cause of knock.
IF we're talking an alloy head here, that is another plus factor for a little higher CR. I guess Bayrunner needs to specify the details of this build.
Adios, David