Howdy:
The '82 Zephyr head is a great candidate for a rebuild and use on your engine. The only smog issue on the '82 head is a window on the side of the log below the carb mount. You will need to make a cover for it. It is easy.
In 1982 the 200 head and the 250 head are identical. The only year(s) where they were not identical is probably 1969 , and then only with the "M" suffix castings. From 1970 - 74, things were very mixed with what went on what. We have found pre "M" castings on 250s and "M" castings on 200s. ??????? So, NO, in 1982 there is no advantage to a 250 head.
In your case an exhaust port divider benefit will be marginal. I'm one who believes in them, even for a small benefit in evening the flow from cylinder to cylinder. If I were doing a performance upgrade for a cylinder head for a boat like yours, I'd take the time to tightly fit a divider and have it welded in prior to machining. That's my two cents, for what it's worth.
Adios, David