Tank looks really bad for as "new" as it is. . . Just helped a friend get his big generator going. Carb was all gummed up. . Alcohol in gas is ok for daily use, but when it sits its destructive in many ways.
Be overly careful with heat of any kind. Don't make a spark either when it comes loose. . I've seen guys fill the tank with water. This flushes all the vapor out. The weight may help it break loose when you start releasing the silicone too. Not a recommendation per se, just info.