A little off topic here but I fould a PEEK capable printer for relatively cheap. If i get it and it can actually print well then I could make all the adapters/spacers out of peek or pekk which would eliminate the need for phenolic spacers. Aluminum has a heat transfer of about around 205 W/m·K while PEEK and PEEK adjacent materials have about around 0.25-0.29 W/m·K. The pps-cf10 is around .5 because of the carbon fiber in it. But either way a plastic based adapter insulates way better than the metal ones. How long the plastic lasts would be the only potential issue.Aluminum is a good conductor and will also conduct heat to the other side, steel would better, and better if mirror finish on the side to reflect heat away. A barrier of anything would be better than none.
I agree with what Frank said.
Anyone in here know someone who has had experience with PEEK? Not very many people have access to it. Its mostly used by engineering companies.