How are you going to use a wastegate to control boost? Are you going to mount it in the intake?
Seems to me a better option would be a bigger pulley on the S/C. That way you're not driving it faster than you need for your desired boost level and creating a bunch of extra heat.
Also, it's your build and you needn't pay any attention to my unsolicited opinions, but I'd do a simple air/air intercooler before messing with methanol injection. You've already got the supercharger mounted remote from the intake manifold so it'd only be a matter of piping it in....